The Puhipuhi epithermal area, which occurs in a region of graywacke basement partially covered by basalt and lake-bed deposits, is characterized by both large-scale and small-scale geophysical anomalies. Known occurrences of locally intense alteration or silicification are typically associated with strong gravity, resistivity or IP anomalies. Gravity data define a complex negative residual anomaly (up to −50 gu) which has been used to identify and delineate a large area (about 20 km2) of low-density, presumably clay-altered, graywacke basement rocks. This zone, modeled as extending to a few kilometers depth, encompasses, but is more extensive than, the known areas of alteration and has a close spatial association with the basalt cover rocks. Short-wavelength gravity minima and maxima, which indicate that the most intense alteration of the basement rocks occurs below the basalt, correlate, in part, with the inferred location of hydrothermal upflow zones. The control on the location of these zones and their relationship to the location of the basalts is not well known; however, if the basalts acted as a cap rock to the geothermal system, then these areas merit further exploration. High (≥100 ohm-m) and low (≤10 ohm-m) resistivity and high (≥30 mS) IP anomalies occur in association with known silicification, clay alteration and sulfide mineralisation, respectively. In addition, magnetic data help constrain the relative timing of hydrothermal alteration and basaltic volcanism and indicate that mineralisation was broadly synchronous with volcanism. 相似文献
The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level. 相似文献
Ca2SiO4 dicalcium silicate has been transformed at high pressure in a diamond-anvil cell (DAC) coupled with a YAG laser heater, in order to study the high-pressure modifications of this compound. Starting material was the olivine form of Ca2SiO4 (γ-polymorph). Several samples have been synthesized at loading pressures of 4.5, 10 and 15 GPa respectively, at room temperature. Other samples have been obtained at pressures ranging between 4.5 and 45 GPa and temperatures estimated to be about 2500 °C. The study of the quenched high pressure and/or high temperature phases has been performed using analytical transmission electron microscopy (ATEM) and X-ray diffraction (XRD). All the polymorphs of Ca2SiO4 usually produced with high temperatures, including α-Ca2SiO4, have been observed in the samples recovered from the high-pressure experiments. The α′-Ca2SiO4 and α-Ca2SiO4 polymorphs have been obtained at ambient conditions for the first time without stabilizing impurities. A new modification of α′-Ca2SiO4 has also been synthesized. Finally, the breakdown at high-pressure and temperature of Ca2SiO4 into CaSiO3 and CaO is reported. 相似文献
Gravity studies have delineated the largest ultramafic massif in New Zealand, embedded within a buried major SW Pacific crustal suture zone. This suture records terrane collision onto the Gondwana margin during the Mesozoic and separates a forearc terrane from an outboard accretionary prism terrane. It can be traced throughout the length of New Zealand as the Junction Magnetic Anomaly and contains the Permian Dun Mountain Ophiolite Belt, which in the South Island of New Zealand is characterized by a string of isolated ultramafic massifs in a sheared matrix of serpentinite and sediment. Our analysis reveals a steep gravity gradient at the suture boundary which is attributed to a newly recognised density contrast (0.1 Mg m− 3) between terranes of the forearc and the accretionary prism. The massif itself is marked by the occurrence of a strong, elongate residual gravity anomaly (+ 120 g.u.) extending 50 km along the suture and coincident with the Junction Magnetic Anomaly. It is modelled, at its southern end, as a dense, 15 km wide source body, extending to at least 6 km in depth. In conjunction with detailed aeromagnetic data, this modeling indicates the presence of a spindle-shaped ultramafic massif, analogous to, but larger than similar bodies found within the Dun Mountain Ophiolite Belt elsewhere. This fabric of sheared serpentinites enclosing ultramafic massifs therefore extends at least the length of New Zealand and probably beyond. In part it may result from accretion of asperities in the subducting plate, but it is also due to disruption of larger ultramafic bodies during subsequent strike-slip motion, which caused the remarkable linearity of the Dun Mountain Belt. Given the common occurrence of the plate tectonic processes involved, it is likely that such structures can be found in other regions around the world using similar geophysical potential field methods. 相似文献
Summary Previous studies on propagating rifts suggested that segmentation of a spreading axis could represent the superficial mark of mantle behavior (Sinton et al., 1983; Nicolas, 1989; Gente et al., 1995). The study of North–South Propagating Spreading Center (NS-PSC) from the North Fiji Basin (NFB) brings new insights to this debate. Basalts from the central part of the propagator have more variable incompatible and isotopic ratios then those from its northern tip. A model of dynamic partial melting of a thermally and slightly geochemically and isotopically heterogeneous mantle is proposed. Beneath the central segment, the partial fusion starts deeper (ca. 30km) and reaches a higher rate (ca. 22%). Further open system differentiation occurs within shallow permanent magma reservoirs along most of the central segment. Below the segment closest to the tip of the propagator the partial fusion starts shallower (ca. 25km) and stays at a lower rate (ca. 16%). The maximum of differentiation occurs close to the propagator, in small, periodically disconnected, magma bodies resulting in the production of ferrobasalts close to the tip. In order to explain these variations, the presence of an asthenospheric diapir focused beneath the central part of the NS-PSC is proposed. The petrogenetic processes of propagating spreading centers of mature oceanic basins or back-arc basins are identical. 相似文献
The seasonal variability of sea surface height (SSH) and currents are defined by analysis of altimeter data in the NE Pacific Ocean over the region from Central America to the Alaska Gyre. The results help to clarify questions about the timing of seasonal maxima in the boundary currents. As explained below, the long-term temporal mean of the SSH values must be removed at each spatial point to remove the temporally invariant (and large) signal caused by the marine geoid. We refer to the resulting SSH values, which contain all of the temporal variations, as the ‘residual’ SSH. Our main findings are:
1. The maximum surface velocities around the boundaries of the cyclonic Alaska Gyre (the Alaska Current and the Alaska Stream) occur in winter, at the same time that the equatorward California Current is weakest or reversed (forming the poleward Davidson Current); the maximum surface velocities in the California Current occur in summer. These seasonal maxima are coincident with the large-scale atmospheric wind forcing over each region.
2. Most of the seasonal variability occurs as strong residuals in alongshore surface currents around the boundaries of the NE Pacific basin, directly connecting the boundaries of the subpolar gyre, the subtropical gyre and the Equatorial Current System.
3. Seasonal variability in the surface velocities of the eastward North Pacific Current (West Wind Drift) is weak in comparison to seasonal changes in the surface currents along the boundaries.
4. There is an initial appearance next to the coast and offshore migration of seasonal highs and lows in SSH, alongshore velocity and eddy kinetic energy (EKE) in the Alaska Gyre, similar to the previously-described seasonal offshore migration in the California Current.
5. The seasonal development of high SSH and poleward current residuals next to the coast appear first off Central America and mainland Mexico in May–June, prior to their appearance in the southern part of the California Current in July–August and their eventual spread around the entire basin in November–December. Similarly, low SSH and equatorward transport residuals appear first off Central America and Mexico in January–February before spreading farther north in spring and summer.
6. The maximum values of EKE occur when each of the boundary currents are maximum.
Article Outline
1. Introduction and background
2. Data and methods
2.1. Altimeter and tide gauge data
2.2. Atmospheric forcing—sea level pressure
2.3. Statistical gridding
3. Results
4. Summary and discussion
4.1. Alaska Gyre
4.2. Connections around the boundaries of the subarctic and subtropical gyres
4.3. Connections to the North Pacific Current
4.4. Offshore ‘propagation’ of the seasonal height and transport signals
4.5. Connections to the equatorial current systems along the boundaries
Acknowledgements
References
1. Introduction and background
This is the first of a two-part analysis of temporal variability of the NE Pacific Ocean’s surface circulation, as measured by satellite altimeters. Here we examine the seasonal variability. In Part 2 (Strub & James, 2002) we analyze the non-seasonal anomalies of the surface circulation over the 1993–1998 period, during which the 1997–1998 El Niño creates the largest signal. Formation of the seasonal cycles discussed here is the first step in creating the non-seasonal anomalies. The seasonal cycles themselves, however, provide new information on the response of the NE Pacific to strong seasonal forcing, on scales not previously addressed. This analysis quantifies the degree of connection, on seasonal time scales, between the boundary currents in the eastern subarctic and subtropical gyres, as well as the connection between the boundaries and the interior NE Pacific. It further shows a connection to the equatorial current system.Numerous papers describe aspects of the seasonal cycles for certain parameters in subregions of our larger domain. Chapters in Robinson and Brink (1998) review some of the past results from the coastal ocean in the regions between the Equator and the Alaska Gyre ( Badan; Hickey and Royer). Fig. 1 presents the climatological surface dynamic height field (relative to 500 m) in the NE Pacific, calculated from the long-term mean climatological temperature and salinity data of Levitus and Gelfeld (1992). The 500 m reference level is used to concentrate on the surface flow seen by altimeters. Although this climatology is overly smooth, it shows the major currents in the area. The broad, eastward North Pacific Current (also called the West Wind Drift) splits into the counterclockwise Alaska Gyre and the equatorward California Current. South of 20°N in summer, the California Current turns westward and flows into the North Equatorial Current, while in winter–spring, part of it continues along the Mexican mainland before turning westward ( Badan; Fiedler and Fiedler). The long-term climatology shows both paths. The North Equatorial Countercurrent (NECC) flows eastward between 5° –10°N to approximately 120°W, but is only weakly seen in the annual climatology from there to the cyclonic flow around the Costa Rica Dome near 8°N, 92°W. The NECC is a shallow current (found in the upper 200 m) and might appear more strongly if a shallower reference were used, but it is also seasonally intermittent. When the Intertropical Convergence Zone (ITCZ) is in its northern location near 10°N (summer), surface divergences and upwelling create a zonal trough in surface height, driving the NECC along the southern side of the trough. When the ITCZ moves south in winter, the NECC weakens or reverses. 相似文献
We present an analysis of the rainfall-evaporation-atmospheric moisture cycle in a semi-arid tropical zone (southwestern Madagascar) to quantify the recycling and mixing processes that occur above an endorheic lake system (Lake Ihotry) during an annual cycle. The study combines an isotope mass balance with a detailed field investigation of the lake system and a previously established daily time-step lake water balance model. The mass balance and Craig-Gordon equations are used to calculate the isotopic composition of the evaporative flux from the lake surface (δE) and to derive a daily time series of the ambient atmospheric water vapour composition above the lake (δAL) during a 8-month dry season. Calculated δAL results from a mixing between regional moisture (δAR) and locally evaporated water (δE), the latter representing 50% of δAL at the end of the dry season. The contribution of recycled moisture to on-lake precipitation during the wet season is estimated to ?16%. We show that, as expected, the deuterium excess is high in recycled precipitation and low in evaporated precipitation, but also that the recycled moisture in an endorheic system may have a low deuterium excess resulting from the low deuterium excess in regional precipitation. In case of a long evaporative season, the atmospheric moisture is not in isotopic equilibrium with the annual composition of precipitation because of the contribution of the recycled vapour to the local atmospheric pool. Our approach demonstrates the importance of water recycling on the atmospheric moisture cycle and precipitation in a tropical semi-arid system, and can be applied to other natural systems, enlarging the potential range of investigation of the atmospheric vapour cycle and rainfall sources in tropical lands. It may also represent a valuable complement to direct water vapour sampling, in yielding the long-term evolution of the atmospheric vapour composition with spatially averaged values and smoothed temporal variations. 相似文献
Several laboratory studies have recently demonstrated the utility of geophysical methods for the investigation of microbial-induced changes over contaminated sites. However, it remains difficult to distinguish the effects due to the new physical properties imparted by microbial processes, to bacterial growth, or to the development of bacterial biofilm. We chose to study the influence of biofilm formation on geophysical response using complex conductivity measurements (0.1-1000 Hz) in phenanthrene-contaminated media. Biotic assays were conducted with two phenanthrene (PHE) degrading bacterial strains: Burkholderia sp (NAH1), which produced biofilm and Stenophomonas maltophilia (MATE10), which did not, and an abiotic control. Results showed that bacterial densities for NAH1 and MATE10 strains continuously increased at the same rate during the experiment. However, the complex conductivity signature showed noticeable differences between the two bacteria, with a phase shift of 50 mrad at 4 Hz for NAH1, which produced biofilm. Biofilm volume was quantified by Scanning Confocal Laser Microscopy (SCLM). Significant correlations were established between phase shift decrease and biofilm volume for NAH1 assays. Results suggest that complex conductivity measurements, specifically phase shift, can be a useful indicator of biofilm formation inside the overall signal of microbial activity on contaminated sites. 相似文献
The inorganic manufactured nanoparticles as TiO2, Ag°, the iron oxides and CeO2 are more and more present in various manufactured products and in the aqueous media (TiO2). Their dispersion in the ecosystems during their life cycle will be associated with interactions with biota (plants, bacteria, fishes). The present work shows strong relations between particular physical chemical properties of very small nanoparticles (size < 30 nm) and biological activity perturbations. It is shown that Ag° and CeO2 act at very low concentrations. TiO2 act via the ROS production due to their photo-reactivity. 相似文献
